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Ingredients9 min readJanuary 4, 2025

Chemical Exfoliants: AHAs vs BHAs Explained

Understand the difference between alpha hydroxy acids and beta hydroxy acids, when to use each, and how to incorporate them safely into your routine.

Dr. Sarah Chen

Dr. Sarah Chen

Board-Certified Dermatologist

Chemical Exfoliants: AHAs vs BHAs Explained

Chemical Exfoliants: AHAs vs BHAs

Chemical exfoliants are powerful tools for achieving smoother, clearer skin. Understanding the difference between AHAs and BHAs helps you choose the right exfoliant for your specific concerns.

Alpha Hydroxy Acids (AHAs) - Water-Soluble, Surface Action

AHAs work by breaking down the "glue" (desmosomes) holding dead skin cells together, promoting even resurfacing.

AHA Type Source Molecular Size Strength Best For
Glycolic Acid Sugarcane Smallest Strongest All skin types, most effective penetration
Lactic Acid Milk Medium Gentle Sensitive skin, hydration + exfoliation
Mandelic Acid Almonds Largest Mildest Very sensitive skin, rosacea-prone
Citric Acid Citrus Small Moderate Brightening, antioxidant properties

Concentrations: 5-10% for home use, up to 30% in professional peels Dermatologist Agreement: 91.9% for dark spots (glycolic acid)

Beta Hydroxy Acids (BHAs) - Oil-Soluble, Pore-Penetrating

The key differentiator: BHAs are lipophilic, allowing them to penetrate through sebum into pores.

Salicylic Acid

Most common BHA, derived from willow bark. Anti-inflammatory properties make it ideal for acne.

  • Standard concentrations: 0.5-2% (leave-on), up to 10% (wash-off)
  • Betaine Salicylate

    Gentler alternative; 4% betaine ≈ 2% salicylic acid

    Dermatologist Agreement: 93.6% for acne (salicylic acid)

    Key Differences

    Factor AHAs BHAs
    Solubility Water-soluble Oil-soluble
    Penetration Surface Deep into pores
    Best for Dullness, hyperpigmentation, fine lines Blackheads, whiteheads, oily skin
    Sun sensitivity Higher increase Lower increase
    Ideal skin type Dry, sun-damaged, aging Oily, acne-prone

    How to Use Chemical Exfoliants

    Starting Protocol

  • Begin with 2-3 times per week
  • Apply to clean, dry skin
  • Wait 20-30 minutes before other products
  • Always follow with moisturizer
  • Sunscreen is essential (especially with AHAs)
  • Can You Combine AHAs and BHAs?

    Yes! You can:

  • Use BHA in AM, AHA in PM
  • Alternate days
  • Use products that combine both (at lower concentrations)
  • Signs of Over-Exfoliation

  • Persistent redness or irritation
  • Increased sensitivity
  • Dry, flaky patches
  • Breakouts in unusual areas
  • Stinging with normally tolerated products
  • If you experience these, stop exfoliating and focus on barrier repair for 2-4 weeks.

    The Bottom Line

    AHAs and BHAs serve different purposes. AHAs excel at surface renewal and brightness, while BHAs dive deep to clear pores. Most people can benefit from using both strategically.

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    Tags

    AHABHAglycolic acidsalicylic acidexfoliationchemical exfoliants

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